Activated zeolite powders

Due to contain electricity price low ionic radius larger metal ions and combining state of the water, the water Activated zeolite powders in the heated continuously losing, but crystal skeleton structure remains the same, has formed many of the same size of the cavity, the cavity has many of the same diameter pores is linked together, these small cavity diameter size uniform, can channel diameter smaller than the 4a zeolite powder to the interior of the cavity, and channel than large molecules are excluded, so the molecules of different diameter size shape, the degree of different polarity molecules, the boiling point of different molecules, degree of saturation of different molecular separation, which have the function of the "screening" molecules, known as molecular sieve. The molecular sieve in metallurgy, chemical industry, electronics, petrochemical, natural gas and other widely used in industry.

The kinds of molecular sieve 4a

molecular sieve 4a has two kinds of natural zeolite and synthetic zeolites. (1) most of the natural zeolite by volcanic tuff and gray matter in the Marine sedimentary rocks coagulation or react to form in the lacustrine environment. Has now found that more than 1000 kinds of zeolite ore, more important is 35 kinds, common clinoptilolite and mordenite, erionite and ling zeochem molecular sieves, etc. Mainly distributed in the United States, Japan, France and other countries, China is also found that there is a lot of mordenite and clinoptilolite deposits, Japan is the largest country in the production of natural zeolite. (2) by natural zeolite resource constraints, starting in the 1950 s, a large number of the synthetic zeolite.

Commodity molecular sieve common prefix digital classifying crystalline structure of different molecular sieves, such as 3 a, 4 a, 5 a molecular sieve. 4 A type or class A in the table, aperture 4 A. Type A molecular sieve as containing Na + Na - A, if one was Na + K + displacement, pore size is about 3 A, namely type for 3 A molecular sieve; If there is more than A third in the Na - A Na + Ca2 + displacement, pore size of about 5 A, is the type 5 A molecular sieve.

natural gas drying,grace molecular sieves

natural gas drying is amorphous silicate or silicon aluminate, made of silicon oxygen tetrahedron or alumina tetrahedron by oxygen bridge is linked together to form a molecular size (usually from 0.3 to 0.3 nm) of concreted complete cavity system, which are characteristic of molecular sieve. However, with the deepening of the molecular sieve synthesis and application research, the researchers found that the phosphorus aluminate salts molecular sieve, grace molecular sieves and the skeleton of elements (silicon or aluminum or phosphorus) can also Be composed of B, Ga, Fe, Mn, Cr, Ge, Ti, V, Co, Cu and zinc, Be replaced, the concreted complete cavity also can achieve more than 2 nm, the size of the molecular sieve can Be divided by skeleton elements silicon aluminum type molecular sieve, phosphorus kind of molecular sieve and skeleton heteroatomic molecular sieve; According to the hole size, hole size less than 2 nm, 2 ~ 50 nm, and more than 50 nm molecular sieve respectively called microporous and mesoporous and macroporous molecular sieve. With large aperture, become a good carrier of larger molecular reaction, but for amorphous mesoporous materials of hole wall, causing its water thermal stability and thermal stability is not required for petrochemical industry application harsh conditions.

Molecular sieve powder

Molecular sieve powder is a kind of crystal type of aluminum silicate, the crystal structure of neat and uniform pore size was in the order of molecular size, it only allows molecules into the smaller than the aperture diameter, so can according to the size of the molecules in the mixture screening. According to molecular sieve. As early as 200 years ago, b. g dragon, he named the first activated zeolite, the chemical composition in the general formula for molecular sieve zeolite molecular sieve type M and n are metal ions and the valence; X is the silica on the number of molecules; Y is the number of molecules of water; P is aluminum atomic number; Q is number of silicon atoms. Molecular sieves in chemical industry as a solid adsorbent, by adsorption material can desorption, molecular sieve can be recycled after use. Is also used in gas and liquid, dry, purification, separation and recycling. In the 1960 s, used as cracking catalysts in the petroleum refining industry, has now developed a variety of suitable for different molecular sieve catalysts for catalytic process.

4A molecular sieve properties function

 Water softening ion exchange performance features: 4A molecular sieve framework are each oxygen atom is shared by two adjacent tetrahedra, this structure which may be occupied by cations and water molecules large bugholes, and these cations and water molecules have a greater mobility, cation exchange and reversible dehydration. 4A zeolite is ion exchange with aluminum ions in the framework carried a negative charge carried by each of the aluminum ions, may be not only sodium ions, may also be combined with other cations. Calcium and magnesium ions can enter the original sodium ions occupy a large crystal cave, the 4A Zeolite replace sodium ions 4A Zeolite down ---- that sodium ions can be exchanged with hard water Ca2 + ,, Mg2 + ions exchange, so as to achieve the purpose to soften water.
Combined with calcium and magnesium ions in zeolite 4A speed slower than sodium tripolyphosphate, and with the ability to bind magnesium ions is weak. But 4A molecular sieve can be a small amount of water in harmful heavy metal ions (such as Pb2 +, Cd2 +, Hg2 +) can be very easily and quickly removed to purify water has very important significance.
---- Carrier liquid of adsorptive functional surfactant: As 4a molecular sieve crystals of the hole structures, plus fine particles having a large specific surface area, so the strong adsorption performance of 4A molecular sieve.
Adsorption of non-ionic surfactants, 4a molecular sieve 3 times NTA (nitrilo-triacetate) and sodium carbonate, five times the sodium tripolyphosphate (STPP) and sodium sulfate, and the nature of the molding for the agglomeration production of high-concentrated detergent formulated with more surfactants, washing and flow properties obtained good product makes sense. Through the experiment, liquid Zeolite 4A carrying capacity ≥30%, 4A molecular sieves in the detergent production process, increase the mobility of the material, to adjust the viscosity, obtained product appearance, sexual fluidity and anti-caking good product.
Detergency: experiments with different additives on the same formula, changing its detergency aid comparison, found 20% of the STPP, 20% of the molecular sieve, 4% polymer and 40% of the decontamination effect STPP rather, in 20% of non-phosphorus zeolite added 10% sodium carbonate and 4.5% of the polymer obtained very good detergency products.
Redeposition properties: 4a molecular sieve 

with good adhesion of oil, when sodium carbonate, CMC, sodium silicate and sodium and other additives added zeolite adsorption decreased nylon fabric for oil pollution. Particle size of the zeolite at 0.4-1.0μm, better dispersibility can be prevented from adhering on the fabric.
Although not as good as 4A molecular sieve dispersing ability STPP, but with sodium polyacrylate dispersion can solve complex problems of dirt.
Compatibility with other additives: 4A Zeolite proper performance and other additives can make it complementary, 4A molecular sieve dirt dispersion and hardness ions chelating inferior STPP, but 4A Zeolite mix with STPP, detergency can STPP reached with a single effect. This is because since the solid surface can quickly STPP complex calcium and magnesium ions, and passed through an aqueous medium 4A molecular sieves. 4A Zeolite magnesium ion binding ability, can be obtained by molecular sieve complex silicates, carbonates be compensated.
PH buffer: 4A molecular sieves alkaline PH 1% aqueous solution at 11.0, and therefore has a certain buffer alkalinity.
Safety: 4A Zeolite non-toxic, safe to human height. Eyes, skin irritation, does not cause allergies, safety and reliability. After washing deposited in the soil, does not cause pollution, but also can improve soil, 4A Zeolite no adverse impact on the ecology

Zeolite Introduction

zeolite molecular sieve is a cubic lattice of an aluminosilicate compound having. Molecular sieve has a uniform porous structure, the diameter of its pores of uniform size, these cavities can adsorb molecules smaller diameter than the internal bore, and an unsaturated polar molecules and molecules having a preferential adsorption capacity, and thus able to very different degree, different degree of saturation, and boiling points of different molecular sizes of different molecules separated, that has the effect of "screening" elements, so called molecular sieves. Since the molecular sieve dryer have a high adsorption capacity, high thermal stability other adsorbents that are not so widely applied molecular sieve.

In the field of biological macromolecules, a common bio-rad SEC sieve prepacked columns.
US scientists have found that by adjusting the temperature, to precisely control one titanium silicate material pore size, to create a sophisticated molecular sieve. Some internal crystal material has a large number of uniform pore size smaller than the molecules can pass through the holes, while large molecules can not pass through, and thus serves to separate different 4a molecular sieves , such materials are known as molecular sieve.

Molecular sieve functions and features

The porous material has been widely used in many fields, such as the main catalytic microporous molecular sieve material, adsorption and ion exchange material separation materials plays an increasingly important role in oil processing, petrochemicals, fine chemicals, and household chemicals .
Molecular sieves (also known as a synthetic zeolite) is a microporous aluminosilicate crystalline silicon. It is made of silicon oxide, aluminum oxide tetrahedra basic skeleton structure, there is a metal cation in the crystal lattice (such as Na +, K +, Ca2 +, Li +, etc.), in order to balance the negative charge excess crystals. According to their type of zeolite crystal structure is divided into: A type, X-type, Y type.
Zeolite relevant standards:
"3a molecular sieve" "4A molecular sieve" "5a molecular sieve and test methods" "13X molecular sieve"

"Water assay method static sieve" "sieve dynamic water assay method"
"Granular sieve size determination," "Determination of bulk density of molecular sieve" "sieve crush strength test method", "Standard Test Method for molecular sieve desiccant cooling systems with anti-wear performance," "Determination of dynamic zeolite adsorption of carbon dioxide."
"Industrial activated alumina," "air separation plant with activated alumina acceptance technical conditions"
(5) Pharmaceutical ---- silver zeolite antimicrobial agent.

Molecular sieve chromatography

molecular sieve chromatography, also known as gel or gel filtration chromatography. Gel filtration is the use of a certain pore size range of porous gel as the stationary phase, the components of the mixture according to molecular size separating chromatographic technique. A substance having a 13x molecular sieves action are many, such as pumice, agar, agarose, polyvinyl alcohol, polyacrylamide, dextran gels and the like. Sephadex most widely trade name sephadex many models, from G10 to G200, its main applications are: ① fractionation various antigens and antibodies; ② remove complexes of small molecules. Such as desalination, fluorescein and free radioisotopes as well as protein hydrolysis fragments; ④ Determination of the molecular weight; ③ Analysis of immune complexes in serum.